![]() ![]() Even dealers are more welcoming during this time of year. The best time to buy is January, so instead of buying yourself Christmas gifts (we all do it) save that money and put it to good use when everyone else needs cash. There are better times of the season to buy but you’ll have to plan ahead and go against the grain just a bit. Warm summer days call out the biker in us all, but they also can drive prices higher than ever. Take advantage of motivated private sellers and dealers On these NOS units the mileage may not show as technically they should have 0 miles.Ģ) Timing is everything. Underneath the price on all listings they show the mileage. Many of the listings will say something like “New” or “Last one available”. What you can find are “New Old Stock (NOS)” motorcycles that are marked down significantly. Search and browse by specific years, 1, 2 or even 3 years older than current. Sales people need to be reminded to get creative, and you can benefit by helping them create the deal you want. Many times dealers have such an abundance of bikes in stock, they leave them crated or stored in the warehouse or even off-site. Second, question your salesperson about left over inventory that might not be on the floor. Consider opting for last year’s model that’s been lingering on the showroom floor. They want to sell their bikes as bad as you want to buy one. Instead remember that dealers need to move old inventory in order to get new inventory from the manufacturers. Here are three tips to get the bike you deserve, at a price you’ll love.Īre you kidding me? Dealers are always more expensive, right? Never use always, those absolutes are your good deal “land mines”. Whatever it is, states like California and Florida tend to have more registered motorcycles, riders and demand than other states-which could also drive up costs.īut wherever you live, you don’t have to give in to the soaring costs that motorcycle sellers are demanding. About 842,000 motorcycles were registered in California, a popular market for bikers. consumers are still buying around 500,000 motorcycles a year. ![]() Motorcycle sales may be down from what they used to be, but U.S. Helping give riders more freedom to enjoy the bikes they love. The industry organization has teamed up with the Consulate General of Monaco, QVC and the Entertainment Industry Foundation for the networking and fund-raising event, which will feature a silent auction and delicacies from New York restaurant favorites Le Cirque 2000 and Osteria del Circo.Ī portion of the proceeds will benefit the National Women’s Cancer Research Alliance, which was founded by Lilly Tartikoff.Clint Lawrence, founder of Motorcycle Shippers. ![]() MONACO CONNECTION: The beauty of the Cote d’Azur is the guiding theme for the Accessories Council’s “March in Monaco” party, to be held March 6 at the Marchon Showroom at 8 West 40th Street in Manhattan. Maria Turgeon, who has shown her line of handbags and weekenders from a showroom at 152 West 27th Street, has handed over wholesale sales to Cynthia O’Connor & Co. Accessories, which represented Lulla’s handbag and scarf firm, Bindya Accessories.īesides the Bindya line, Pure will represent Summer Tompkins handbags, Piu Natura scarves, Langston Bourquin hats, jewelry by Lapis Lois and hair accessories by Mei Fa. Until recently, Lindholm was an account executive at D.P. “We thought we were better together.”ĭale Lindholm and Bindya Lulla are opening Pure Accessories, a 1,500-square-foot space at 389 Fifth Avenue. “We share a lot of clients, we are always referring people to each other,” said Natt. The combined entity will offer retailers Capital A lines such as Cynthia Rose, Stephanie Johnson and Temma Dahan, alongside Sola’s Bajra, Dorian Webb and Pazuki. Both companies still operate as separate entities, though they are planning to cooperate on marketing and sales, according to Sola’s owner Lisa Natt. Among them:Ĭapital A has relocated and moved in with Sola at its 162 Fifth Avenue offices. SHOWROOM SHUFFLE: As next week’s transition market in New York approaches, a number of showroom moves have been made. ![]()
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![]() ![]() Read each problem carefully to identify what quantities are given, including their unit of measure, and to identify what is unknown.The change in each quantity must be in agreement with the reaction stoichiometry.Use equilibrium quantities in calculations involving the equilibrium constant, K.Use initial quantities when calculating the reaction quotient, Q, to determine the direction the reaction shifts to establish equilibrium.(If using K p, gaseous species must be expressed in appropriate pressure units.) ![]() ![]() Express all quantities in terms of MOLARITY (moles per liter).In making an ICE chart the following items should be noted: The oxidation-reduction reaction occuring between iron(III) chloride and tin(II) chloride.The thermal decomposition of calcium carbonate.The production of ammonia from nitrogen and hydrogen gases.When one or more gaseous substances are involved, the K p expression is also given. When one or more of the species in a system exists in the gaseous phase, the partial pressure of that species can be used in the equilibrium expression Dissolved species are still expressed as moles per liter (molarity).Įxamples of equilibrium expressions K c for a variety of equilibrium systems follow. There are two cases when a species is not shown in the equilibrium expression: The "c" in K c indicates that the value of K is determined using the concentrations of each species. "a, b, c, and d" represent the coefficients used to balance the equation. The brackets "" represent the concentration of the species (moles per liter or molarity). The general equilibrium expression for a reaction: Then we convert to grams to find the amount of oxygen that needs to be added: Then, because there are five (5) molecules of oxygen to every two (2) molecules of C 2H 2, we need to multiply the result by 5/2 to get the total molecules of oxygen. Therefore we know that 1 mole of C 2H 2 weighs 26 g (2 × 12 grams + 2 × 1 gram). To be able to calculate the moles we need to look at a periodic table and see that 1 mole of C weighs 12.0 g and H weighs 1.0 g. To solve this problem, it is necessary to determine how much oxygen should be added if all of the reactants were used up (this is the way to produce the maximum amount of CO 2).įirst, we calculate the number of moles of C 2H 2 in 6.0 g of C 2H 2. If she uses the equation below, how much oxygen should she add to the reaction?ĢC 2H 2(g) + 5O 2(g) -> 4CO 2(g) + 2 H 2O(l) Often, it is necessary to identify the limiting reagent in a problem.Įxample: A chemist only has 6.0 grams of C 2H 2 and an unlimited supply of oxygen and he desires to produce as much CO 2 as possible. Sometimes when reactions occur between two or more substances, one reactant runs out before the other. How many moles of Ca are in 4.50 grams of Ca?Ĭitation: Department of Chemistry at UNC Chapel Hill at Molar Mass of Ca = 40.08 (From the Periodic Table) So, 40 grams of calcium makes one mole, 80 grams makes two moles, etc. For example, calcium has an atomic mass of 40 atomic mass units. Given the atomic or molecular mass of a substance, that mass in grams makes a mole of the substance. This conversion can be easily done when the atomic and/or molecular mass of the substance(s) are known. Thus, you have the same number of moles of AgNO 3, NaCl, AgCl, NaNO 3.Ĭonverting between moles and grams of a substance is often important. ![]() In the equation above there are no numbers in front of the terms, so each coefficient is assumed to be one (1). Similarly, if you have a mole of carrots, you have 6.022 x 10 23 carrots. If you have a dozen carrots, you have twelve of them. A mole is similar to a term like a dozen. Given enough information, one can use stoichiometry to calculate masses, moles, and percents within a chemical equation.Ī mole simply represents Avogadro's number (6.022 x 10 23) of molecules. Stoichiometry is simply the math behind chemistry. ![]() ![]() Zipster black cat costume skin#However, just as there is more than one way to skin a cat, there are also a variety of costumes that cat lovers can wear for Halloween.Īre you thinking about wearing a cat costume for a party, but you’re having trouble choosing which breed of cat best represents who you are? The following is a synopsis of some of the more well-known species of cats that can be found in the animal kingdom. If you are thinking about wearing a costume with leopard print, the most obvious choice for the man in your life to wear is a Tarzan costume.Įveryone is familiar with the typical domesticated housecat. Those individuals who adore children in addition to cats will find it to be an ideal option. If you approach the children while dressed in the costumes, they will go absolutely NUTS with excitement. If he really is something special, he might already have something in the back of his closet that he can use for the costume! If not, there is a large variety of different options for pimp costumes that can be found online and purchased for the big day. This Halloween costume goes particularly well with the pimp costume, which is why we recommend wearing it. If you want to celebrate Halloween in a seductive cat costume, there won’t be much room for your significant other to manoeuvre if he also wants to dress up as a cat for the holiday. Why not try to put together as many different Halloween costumes as you can and compete for the title of best group costume if you have a large number of close friends and are interested in celebrating Halloween together? Pimp and Sex Kitten Poison Ivy, a female Robin costume, Batwoman, Batgirl, and a female Robin costume are some of the other options for women. Zipster black cat costume movie#Robin, the Joker, the Riddler, the Penguin, and Two-Face are some of the other potential male characters from the Batman movie and comic book series that could be cast. On the other hand, if you don’t want to, you don’t have to limit your superhero party to just those two characters. Their relationship has been depicted in a number of comic books and animated shows. ![]() ![]() The fact that Batman and Catwoman have a romantic history together makes it a great idea for a couple to dress up as the two of them for Halloween. ![]() Since you are currently browsing our website, it is reasonable to assume that you have given some consideration to the possibility of celebrating Halloween in the guise of Catwoman at some point in the past. You can wear this outfit alone or pair it with a lovely cat woman to accompany you. ✅ This batman costume is breathable, and makes you look strong. ![]() |
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